Reactivity 3 / IB Chemistry / Reactivity 3.4 (SL + HL)
Reactivity 3.4—Electron-pair sharing reactions
Reactivity 3.4.1—A nucleophile is a reactant that forms a bond to its reaction partner (the electrophile) by donating both bonding electrons.\
Reactivity 3.4.2—In a nucleophilic substitution reaction, a nucleophile donates an electron pair to form a new bond, as another bond breaks producing a leaving group.
Reactivity 3.4.3—Heterolytic fission is the breakage of a covalent bond when both bonding electrons remain with one of the two fragments formed.
Reactivity 3.4.4—An electrophile is a reactant that forms a bond to its reaction partner (the nucleophile) by accepting both bonding electrons from that reaction partner.
Reactivity 3.4.5—Alkenes are susceptible to electrophilic attack because of the high electron density of the carbon–carbon double bond. These reactions lead to electrophilic addition.
Reactivity 3.4.6—A Lewis acid is an electron-pair acceptor and a Lewis base is an electron-pair
Reactivity 3.4.7—When a Lewis base reacts with a Lewis acid, a coordination bond is formed. Nucleophiles are Lewis bases and electrophiles are Lewis acids.
Reactivity 3.4.8—Coordination bonds are formed when ligands donate an electron pair to transition element cations, forming complex ions.
Reactivity 3.4.9—Nucleophilic substitution reactions include the reactions between halogenoalkanes and nucleophiles.
Reactivity 3.4.10—The rate of the substitution reactions is influenced by the identity of the leaving group.
Reactivity 3.4.11—Alkenes readily undergo electrophilic addition reactions.
Reactivity 3.4.12—The relative stability of carbocations in the addition reactions between hydrogen halides and unsymmetrical alkenes can be used to explain the reaction mechanism.
Reactivity 3.4.13—Electrophilic substitution reactions include the reactions of benzene with electrophiles.








