This PowerPoint lesson develops a clear understanding of expanded octets and VSEPR theory, enabling Higher Level IBDP Chemistry students to predict molecular geometry beyond the octet rule. Designed for first assessment 2025, it provides structured guidance for drawing Lewis structures and deducing three-dimensional shapes for species with five and six electron domains.
The octet rule states that atoms tend to achieve eight electrons in their outer shell, but this rule has important exceptions. In this lesson, students explore expanded octets, where central atoms from period 3 or below accommodate more than eight valence electrons, and briefly review incomplete octets. Clear definitions of terms such as electron-deficient and expanded octet are included to strengthen exam precision.
Step-by-step methods are provided for constructing Lewis formulas, calculating total valence electrons, identifying central atoms, and correctly assigning lone pairs. The lesson then applies VSEPR (Valence Shell Electron Pair Repulsion) theory to determine electron-domain geometry and molecular geometry. Five-domain shapes (trigonal bipyramidal, see-saw, T-shaped, linear) and six-domain shapes (octahedral, square pyramidal, square planar) are explained using worked examples such as SF₄, ClF₃, I₃⁻, PF₆⁻, BrF₅ and XeF₄.
Approximate bond angles are predicted using VSEPR, with clear emphasis that IB exams require model-based predictions rather than experimental values. The distinction between electron-domain geometry and molecular geometry is consistently reinforced.
The PowerPoint includes starter activities, structured examples, geometry summaries, and practice questions suitable for HL teaching, consolidation, or revision.
File type included: PowerPoint (.pptx)
Last updated: January 2026 – Lewis structure steps clarified, VSEPR shapes expanded, and HL scope checked against the 2025 IB Chemistry syllabus.
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